The BBC replays don't actually show this and I'm having difficulty finding a replay on YouTube as FIFA are pretty strict about removing any footage that's uploaded, but, from what I can recall, Müller did react to the "headbutt" by whipping his head back before rising to his feet to remonstrate with Pepe. It was a delayed movement not directly caused by any head motion of Pepe's, but I can't be sure whether Müller was trying to give the appearance that greater force had been exerted upon him by Pepe's head or whether he was just innocently pulling his head back from Pepe's to get away from the situation (before launching in again with a verbal attack once on his feet again, of course).
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