That's quite an assumption. It is possible to buy flights from the Airlines at Airports. But the customers are expected to be business travellers, passengers having to change plans or need to travel urgently. The airline desks may only have authority to sell flights under the main prices like Y for economy, C is one business class. Those economy seat prices advertised maybe X, Q, W those seats might be gone or nobody will sell them to you at the airport. Those classes usually have retrictions on how late then can be sold aswell.
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